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Photo Chemicals

Analog photography shops are becoming scarce, it may become difficult to find the chemicals and preparing them out of raw chemicals is advantageous.

If, for color work, it's a bit complex due to difficult to find chemicals, the story is much easier to make them for B/W work.

Main advantages are:

Drawbacks are:

Required hardware is the following:

Where could you find the formulas ?

Where to find the chemicals ?

This is extremely variable from a country to another, you can start by looking at following shops:

Photo Forums

You can also ask on some forums specialized in analog photography, like:

And a mailing-list where you'll find pretty advanced folks:

What chemicals do I use ?

Kodak X-Tol has no published formula but two reasonably close equivalents are often mentioned:
MyTol

 

Chemical Quantity Comments
Water 750ml  
Sodium Sulfite 60gr   Anhydrous
Sodium Metaborate 4gr  
Sodium Ascorbate 13gr or 11.6gr ascorbic acid
Phenidone 0.15gr  
Sodium Metabisulfite 3gr  
Distilled water to make 1000ml  
DS-10

Increase development durations by 20% compared to genuine X-Tol.

Chemical Quantity Comments
Water 700ml  
Sodium Sulfite 75.0gr Anhydrous
Triethanolamine 10ml 99%
Ascorbic acid 8.0gr  
Dimezone S 0.15gr  
Salicyllic acid 1.0gr  
Boric acid 4.0gr  
Water to make 1000ml Target pH 8.00 +/- 0.05

D-76

Chemical Quantity Comments
Water 750ml @ 50°C
Metol 2.0gr  
Sodium Sulfite 100.0gr Anhydrous
Hydroquinone 5.0gr  
Borax 2.0gr Granular
Water to make 1000ml  

Rodinal
We can find lots of formulas indicated as being Rodinal, in reality, very few are close to it, so I actually prefer to use commercial products that are really close to the real thing (Adox Rodinal, Calbe R09 One Shot, ...).

D-72

This is a formula published by Kodak and indicated as being very close or even giving identical results compared to their commercial product Dektol.

Chemical Quantity Comments
Water 500ml @ 50°C
Metol 3.0gr  
Sodium Sulfite  45.0gr Anhydrous
Hydroquinone 12.0gr  
Sodium Carbonate 80.0gr Monohydrated
Potassium Bromide 2.0gr Anhydrous
Water to make 1000ml  

E-72

This formula gives results that are nearly identical to D-72 but using less polluting ingredients.
Phenidone does not dissolve in water and because quantities required are very small and could result in measurements errors, it is better to dissolve Phenidone in glycerine, alcool (>90%) or propylene glycol to a ratio of 2, 5 or 10%, and then recalculate the required volume as to get the amount of dry Phenidone as stated in the formula.
You can also replace Phenidone by Metol which is more readily available and simple to use.

Chemical Quantity Comments
Water 750ml at 50°C
Phenidone 0.3gr or 3gr Metol
Sodium Sulfite 45gr anhydrous
Ascorbic Acid 19gr or 21.5gr sodium ascorbate
Sodium Carbonate monohydrated 90gr or 77gr potassium carbonate
Potassium Bromide 1.9gr  
Cold water to make 1000ml  

Stop Bath

Some replace the stop bath by a simple water rinse but I do prefer to keep a real stop bath as to immediately stop the development before fixing..

It is made of a very diluted acid, like citric acid @ 15 gr/l (odorless) or acetic acid (significant smell) you can find in various dilutions from pure (glacial) @ 20ml/l or the more common 28% where you need 48ml/l.
In my case, I chose the citric acid that is more agreable to use than the acetic one.

Fixer

I use an odorless, rapid and neutral fixer that simplifies the following wash sequence.
Papers and films must be washed between the stop bath and the neutral fix to avoid any acidification of the fixer and release of sulphur dioxide that is very disagreeable.

Chemical Quantity Comments
Water 600ml  
Sodium Thiosulfate 360gr crystalline or 230gr anhydrous
Ammonium Chloride 50gr or 60gr ammonium sulfate
Sodium Sulfite 15gr  Anhydrous
Sodium metabisulfite 5gr  
Cold water to make 1000ml pH around 7.0

Wash Aid

The active ingredient of all wash aids is sodium sulfite to which are added several conservatives.
The simplest is to use plain sodium sulfite @ 20gr/l and dump it once your printing session is finished.

Paper Stabilizer

This product improves permanence, especially for fiber papers.
I don't have a formula for this product and use the commercial product Agfa Sistan New.

Film Wetting Agent

Here too, seen the low cost, I prefer to use a commercial product, Tetenal Mirasol 2000, that also contains a biocide/fungicide.

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